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These metabolic pathways form the "energy backend" of the GSH-GSSG cycle, ensuring that GR remains catalytically active, thereby preserving the cell's redox buffering capacity

A previous study reported that vitamin C could prevent monosodium iodoacetate (MIA) induced changes such as cell growth inhibiting and oxidative stress increasing, apoptosis, MMPs increasing, and proteoglycan loss in a chondrosarcoma cell line (SW1353) [160]

This is partly attributed to KPVs entry through colonic cells via PepT1 channels, which are significantly expressed in the intestine primarily during states of inflammation

HMGB1 acts in synergy with lipopolysaccharide in activating rheumatoid synovial fibroblasts via p38 MAPK and NF-B signaling pathways