While smoking side effects on the skin dont directly darken the skin, it can lead to a dull, greyish complexion and uneven skin tone, often referred to as smokers face. This effect is primarily due to the numerous harmful chemicals in cigarette smoke that damage collagen and elastin, crucial proteins for maintaining skin elasticity and brightness
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Wikipedia Curing & Aging Transformations Once leaves are harvested and cured: Oxidation : Phenolics are oxidized, reducing harshness, creating aroma compounds