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The N-termini of VP1-3, as well as the whole of VP4 (N-terminal to VP2 in the VP0 precursor), form a network on the inner surface 2

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(2008) Kinetic and mechanistic characterization and versatile catalytic properties of mammalian glutaredoxin 2: implications for intracellular roles

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This is because it takes time for new skin cells, produced without the inhibitory effects of supplemental glutathione, to move to the visible surface of your skin